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Mass transfer mechanisms in fixed-bed adsorption of erythromycin

SUN Ying, ZHU Jiawen, CHEN Kui, ZHU Sheng, XU Jie

《化学科学与工程前沿（英文）》 2008年 第2卷 第4期   页码 353-360 doi: 10.1007/s11705-008-0076-2

摘要： The equilibrium and kinetic characteristics of the adsorption of erythromycin to Sepabeads SP825 were determined. The equilibrium data in a batch system was well described by a Langmuir isotherm. The separation performance was investigated in a fixed-bed system with respect to the adsorption superficial velocity, ionic strength and pH. A mathematical model was used to simulate the mass transfer mechanism, taking film mass transfer, pore diffusion and axial dispersion into account. The model predictions were consistent with the experimental data and were consequently used to determine the mass transfer coefficients.

关键词： mathematical     diffusion     separation performance     adsorption superficial     mechanism    

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The coupling of sand with ZVI/oxidants achieved proportional and highly efficient removal of arsenic

Sana Ullah, Xuejun Guo, Xiaoyan Luo, Xiangyuan Zhang, Yameng Li, Ziyu Liang

《环境科学与工程前沿（英文）》 2020年 第14卷 第6期 doi: 10.1007/s11783-020-1273-6

摘要： Abstract • Simply doping sands with ZVI achieved an even activation of ZVI by oxidants. • Sand doping facilitated proportional As trapping along the ZVI/oxidants column. • ZVI/sand/oxidants are highly efficient for arsenic removal. • ZVI/sand/oxidants reduced significantly the Fe2+ leaching and effluent turbidity. • More than 54% of arsenic was reduced to As(III) in ZVI/sand/oxidants system. The coupling of zero-valent iron (ZVI) with common oxidants has recently achieved very rapid and highly efficient removal of Heavy metals from wastewater. However, the uniform activation of ZVI throughout the column and the proportional removal of target contaminants are urgently required for the prevention of premature filter clogging and the extension of the effective column operational time. In this study, we successfully achieved this objective by simply doping granular sand with ZVI at appropriate weight ratios. When pure ZVI packed column was spiked with oxidants, the majority of As trapping occurred between the column inlet and the first sampling point. In a packed column with a 1:20 mixture of ZVI and sand, the average As removal efficiency was 36 (1st), 13.1 (2nd), 18.5 (3rd), 19.2 (4th) and 5.9% (5th outlet). The overall arsenic removal performance of the composite filling system of ZVI/sand was equally as efficient as that of the previous pure ZVI-packed system. Moreover, the leaching of Fe was significantly reduced with an increased sand ratio, resulting in clearer water with less turbidity. The results of X-ray photoelectron spectroscopy (XPS) demonstrated that more than 54% of the arsenic was reduced to As(III). X-ray diffraction (XRD) and scanning electron microscopy (SEM) confirmed the extensive corrosion of the ZVI surface, which resulted in various species of iron oxyhydroxides responsible for the highly efficient sequester of arsenic through reduction, adsorption, and coprecipitation.

关键词： Arsenic     ZVI     Sand     Oxidants     Fixed-bed Column     Removal    

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Recovery of Ni(II) from real electroplating wastewater using fixed-bed resin adsorption and subsequent

Tong Li, Ke Xiao, Bo Yang, Guilong Peng, Fenglei Liu, Liyan Tao, Siyuan Chen, Haoran Wei, Gang Yu, Shubo Deng

《环境科学与工程前沿（英文）》 2019年 第13卷 第6期 doi: 10.1007/s11783-019-1175-7

摘要： • Resin adsorption and subsequent electrodeposition were used for nickel recovery. • Treated wastewater can meet the Electroplating Pollutant Discharge Standard. • The spent resin is completely regenerated by 3 BV of 4% HCl solution. • 95.6% of nickel in concentrated eluent was recovered by electrodeposition. Effective recovery of high-value heavy metals from electroplating wastewater is of great significance, but recovering nickel ions from real electroplating wastewater as nickel sheet has not been reported. In this study, the pilot-scale fixed-bed resin adsorption was conducted to recover Ni(II) ions from real nickel plating wastewater, and then the concentrated Ni(II) ions in the regenerated solution were reduced to nickel sheet via electrodeposition. A commercial cation-exchange resin was selected and the optimal resin adsorption and regeneration conditions were investigated. The resin exhibited an adsorption capacity of 63 mg/g for Ni(II) ions, and the average amount of treated water was 84.6 bed volumes (BV) in the pilot-scale experiments. After the adsorption by two ion-exchange resin columns in series and one chelating resin column, the concentrations of Ni(II) in the treated wastewater were below 0.1 mg/L. After the regeneration of the spent resin using 3 BV of 4% (w/w) HCl solution, 1.5 BV of concentrated neutral nickel solution (>30 g/L) was obtained and used in the subsequent electrodeposition process. Using the aeration method, alkali and water required in resin activation process were greatly reduced to 2 BV and 3 BV, respectively. Under the optimal electrodeposition conditions, 95.6% of Ni(II) in desorption eluent could be recovered as the elemental nickel on the cathode. The total treatment cost for the resin adsorption and regeneration as well as the electrodeposition was calculated.

关键词： Nickel removal     Ion exchange     Electroplating wastewater     Regeneration     Electrodeposition    

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Advances in the slurry reactor technology of the anthraquinone process for H

Hongbo Li, Bo Zheng, Zhiyong Pan, Baoning Zong, Minghua Qiao

《化学科学与工程前沿（英文）》 2018年 第12卷 第1期   页码 124-131 doi: 10.1007/s11705-017-1676-5

摘要： This paper overviews the development of the anthraquinone auto-oxidation (AO) process for the production of hydrogen peroxide in China and abroad. The characteristics and differences between the fixed-bed and fluidized-bed reactors for the AO process are presented. The detailed comparison indicates that the production of hydrogen peroxide with the fluidized-bed reactor has many advantages, such as lower operation cost and catalyst consumption, less anthraquinone degradation, higher catalyst utilization efficiency, and higher hydrogenation efficiency. The key characters of the production technology of hydrogen peroxide based on the fluidized-bed reactor developed by the Research Institute of Petroleum Processing, Sinopec are also disclosed. It is apparent that substituting the fluidized-bed reactor for the fixed-bed reactor is a major direction of breakthrough for the production technology of hydrogen peroxide in China.

关键词： anthraquinone process     fixed-bed reactor     slurry-bed reactor     hydrogen peroxide    

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Migration of manganese and iron during the adsorption-regeneration cycles for arsenic removal

Fangfang CHANG, Jiuhui QU, Xu ZHAO, Wenjun LIU, Kun WU

《环境科学与工程前沿（英文）》 2011年 第5卷 第4期   页码 512-518 doi: 10.1007/s11783-011-0372-9

摘要： Fe-Mn binary oxide incorporated into porous diatomite (FMBO-diatomite) was prepared in situ and regenerated in a fixed-bed column for arsenite [As(III)] and arsenate [As(V)] removal. Four consecutive adsorption cycles were operated under the following conditions: Initial arsenic concentration of 0.1 mg·L , empty bed contact time of 5 min, and pH 7.0. About 3000, 3300, 3800, and 4500 bed volumes of eligible effluent (arsenic concentration≤0.01 mg·L ) were obtained in four As(III) adsorption cycles; while about 2000, 2300, 2500, and 3100 bed volumes of eligible effluent were obtained in four As(V) adsorption cycles. The dissection results of FMBO-diatomite fixed-bed exhibited that small amounts of manganese and iron were transferred from the top of the fixed-bed to the bottom of the fixed-bed during As(III) removal process. Compared to the extremely low concentration of iron (<0.01 mg·L ), the fluctuation concentration of Mn in effluent of the As(III) removal column was in a range of 0.01–0.08 mg·L . The release of manganese suggested that manganese oxides played an important role in As(III) oxidation. Determined with the US EPA toxicity characteristic leaching procedure (TCLP), the leaching risk of As(III) on exhausted FMBO-diatomite was lower than that of As(V).

关键词： arsenic     adsorption     filtration     regeneration     fixed-bed    

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Deactivation and regeneration of TS-1/SiO

Hainan SHI, Yaquan WANG, Guoqiang WU, Wenping FENG, Yi Lin, Teng ZHANG, Xing JIN, Shuhai WANG, Xiaoxue WU, Pengxu YAO

《化学科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 202-209 doi: 10.1007/s11705-013-1328-3

摘要： TS-1/SiO catalyst for the epoxidation of propylene with hydrogen peroxide in a fixed-bed reactor has been investigated. The catalyst activity decreases gradually with the online reaction time, but the selectivity of propylene epoxide is kept at about 93%. The fresh, deactivated and regenerated catalysts were characterized with X-ray diffraction, Fourier transform infrared spectroscopy, ultra-violet-visible diffuse reflectance, Brunner-Emmett-Teller method and thermogravimetric analysis, and the deactivated catalyst was regenerated with H O /methanol solution. Compared with the fresh catalyst, both the framework structure and the content of titanium in the framework of the deactivated and regenerated TS-1/SiO catalysts were not changed. The major reason of the catalyst deactivation was the blockage of the channels of the catalyst by bulky organic by-products, which covered the active centers of titanium in TS-1. The deposited materials on the deactivated TS-1/SiO catalyst could be removed by treatment with hydrogen peroxide/methanol solution or pure methanol; the higher the treatment temperature and the higher the concentration of H O in methanol, the higher the extent of the regeneration. The regeneration treatment did not influence the product selectivity in the propylene epoxidation.

关键词： TS-1/SiO2     epoxidation of propylene     fixed-bed reactor     deactivation     regeneration    

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Reduction of hexavalent chromium with scrap iron in a fixed bed reactor

Yin WANG, Xuejiang WANG, Xin WANG, Mian LIU, Siqing XIA, Daqiang YIN, Yalei ZHANG, Jianfu ZHAO

《环境科学与工程前沿（英文）》 2012年 第6卷 第6期   页码 761-769 doi: 10.1007/s11783-012-0413-z

摘要： The reduction of hexavalent chromium by scrap iron was investigated in continuous long-term fixed bed system. The effects of pH, empty bed contact time (EBCT), and initial Cr(VI) concentration on Cr(VI) reduction were studied. The results showed that the pH, EBCT, and initial Cr(VI) concentration significantly affected the reduction capacity of scrap iron. The reduction capacity of scrap iron were 4.56, 1.51, and 0.57 mg Cr(VI)·g Fe at pH 3, 5, and 7 (initial Cr(VI) concentration 4 mg·L , EBCT 2 min, and temperature 25°C), 0.51, 1.51, and 2.85 mg Cr(VI)·g Fe at EBCTs of 0.5, 2.0, and 6.0 min (initial Cr(VI) concentration 4 mg·L , pH 5, and temperature 25°C), and 2.99, 1.51, and 1.01 mg Cr(VI)·g Fe at influent concentrations of 1, 4, and 8 mg·L (EBCT 2 min, pH 5, and temperature 25°C), respectively. Fe(total) concentration in the column effluent continuously decreased in time, due to a decrease in time of the iron corrosion rate. The fixed bed reactor can be readily used for the treatment of drinking water containing low amounts of Cr(VI) ions, although the hardness and humic acid in water may shorten the lifetime of the reactor, the reduction capacity of scrap iron still achieved 1.98 mg Cr ·g Fe. Scanning electron microscope equipped with energy dispersion spectrometer and X-ray diffraction were conducted to examine the surface species of the scrap iron before and after its use. In addition to iron oxides and hydroxide species, iron-chromium complex was also observed on the reacted scrap iron.

关键词： hexavalent chromium     scrap iron     reduction capacity     drinking water    

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Investigation of fluorescence characterization and electrochemical behavior on the catalysts of nanosized Pt-Rh/γ-Al

Chang-Mao HUNG, Wen-Liang LAI, Jane-Li LIN

《环境科学与工程前沿（英文）》 2013年 第7卷 第3期   页码 428-434 doi: 10.1007/s11783-013-0517-0

摘要： This work describes the environmentally friendly technology for oxidation of ammonia (NH ) to form nitrogen at temperatures range from 423K to 673K by selective catalytic oxidation (SCO) over a nanosized Pt-Rh/γ-Al O catalyst prepared by the incipient wetness impregnation method of hexachloroplatinic acid (H PtCl ) and rhodium (III) nitrate (Rh(NO ) ) with γ-Al O in a tubular fixed-bed flow quartz reactor (TFBR). The characterization of catalysts were thoroughly measured using transmission electron microscopy (TEM), three-dimensional excitation-emission fluorescent matrix (EEFM) spectroscopy, UV-Vis absorption, dynamic light-scattering (DLS), zeta potential meter, and cyclic voltammetry (CV). The results demonstrated that at a temperature of 673K and an oxygen content of 4%, approximately 99% of the NH was removed by catalytic oxidation over the nanosized Pt-Rh/γ-Al O catalyst. N was the main product in NH -SCO process. Further, it reveals that the oxidation of NH was proceeds by the over-oxidation of NH into NO, which was conversely reacted with the NH to yield N . Therefore, the application of nanosized Pt-Rh/γ-Al O catalyst can significantly enhance the catalytic activity toward NH oxidation. One fluorescent peak for fresh catalyst was different with that of exhausted catalyst. It indicates that EEFM spectroscopy was proven to be an appropriate and effective method to characterize the Pt clusters in intrinsic emission from nanosized Pt-Rh/γ-Al O catalyst. Results obtained from the CV may explain the significant catalytic activity of the catalysts.

关键词： ammonia (NH3)     nanosized Pt-Rh/γ-Al2O3 catalyst     excitation-emission fluorescent matrix (EEFM)     selective catalytic oxidation (SCO)     tubular fixed-bed reactor (TFBR)    

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Preparation and characterization of novel carbon molecular sieve membrane/PSSF composite by pyrolysis method for toluene adsorption

Ying Yan, Peng Huang, Huiping Zhang

《化学科学与工程前沿（英文）》 2019年 第13卷 第4期   页码 772-783 doi: 10.1007/s11705-019-1827-y

摘要： Carbon molecular sieve membrane (CMSM)/paper-like stainless steel fibers (PSSF) has been manufactured by pyrolyzing poly (furfuryl alcohol) (PFA) coated on the metal fibers. PFA was synthesized using oxalic acid dihydrate as a catalyst and coated on microfibers by dip coating method. For the purpose of investigating the effects of final carbonization temperature, the composites were carbonized between 400°C and 800°C under flowing nitrogen. The morphology and microstructure were examined by X-ray diffraction, Fourier transforms infrared spectroscopy, scanning electron microscopy, thermogravimetric analysis, N adsorption and desorption, Raman spectra and X-ray photoelectron spectra. The consequences of characterization showed that the CMSM containing mesopores of 3.9 nm were manufactured. The specific surface area of the CMSM/PSSF fabricated in different pyrolysis temperature varies from 26.5 to 169.1 m ∙g and pore volume varies from 0.06 to 0.23 cm ∙g . When pyrolysis temperature exceeds 600°C, the specific surface, pore diameter and pore volume decreased as carbonization temperature increased. Besides, the degree of graphitization in carbon matrix increased with rising pyrolysis temperature. Toluene adsorption experiments on different structured fixed bed that was padded by CMSM/PSSF and granular activated carbon (GAC) were conducted. For the sake of comparison, adsorption test was also performed on fixed bed packed with GAC. The experimental results indicated that the rate constant ′ was dramatically increased as the proportion of CMCM/PSSF composites increased on the basis of Yoon-Nelson model, which suggested that structured fixed bed padded with CMSM/PSSF composite offered higher adsorption rate and mass transfer efficiency.

关键词： carbon molecular sieve membrane     stainless steel fibers     pyrolysis     structured fixed bed     toluene    

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Special Column on

《结构与土木工程前沿（英文）》 2014年 第8卷 第4期   页码 323-324 doi: 10.1007/s11709-014-0288-0

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Simulation of bubble column reactors using CFD coupled with a population balance model

Tiefeng WANG

《化学科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 162-172 doi: 10.1007/s11705-009-0267-5

摘要： Bubble columns are widely used in chemical and biochemical processes due to their excellent mass and heat transfer characteristics and simple construction. However, their fundamental hydrodynamic behaviors, which are essential for reactor scale-up and design, are still not fully understood. To develop design tools for engineering purposes, much research has been carried out in the area of computational fluid dynamics (CFD) modeling and simulation of gas-liquid flows. Due to the importance of the bubble behavior, the bubble size distribution must be considered in the CFD models. The population balance model (PBM) is an effective approach to predict the bubble size distribution, and great efforts have been made in recent years to couple the PBM into CFD simulations. This article gives a selective review of the modeling and simulation of bubble column reactors using CFD coupled with PBM. Bubble breakup and coalescence models due to different mechanisms are discussed. It is shown that the CFD-PBM coupled model with proper bubble breakup and coalescence models and interphase force formulations has the ability of predicting the complex hydrodynamics in different flow regimes and, thus, provides a unified description of both the homogeneous and heterogeneous regimes. Further study is needed to improve the models of bubble coalescence and breakup, turbulence modification in high gas holdup, and interphase forces of bubble swarms.

关键词： bubble column     computational fluid dynamics     bubble breakup and coalescence     population balance model     bubble size distribution    

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Prediction of bed load sediments using different artificial neural network models

Reza ASHEGHI, Seyed Abbas HOSSEINI

《结构与土木工程前沿（英文）》 2020年 第14卷 第2期   页码 374-386 doi: 10.1007/s11709-019-0600-0

摘要： Modeling and prediction of bed loads is an important but difficult issue in river engineering. The introduced empirical equations due to restricted applicability even in similar conditions provide different accuracies with each other and measured data. In this paper, three different artificial neural networks (ANNs) including multilayer percepterons, radial based function (RBF), and generalized feed forward neural network using five dominant parameters of bed load transport formulas for the Main Fork Red River in Idaho-USA were developed. The optimum models were found through 102 data sets of flow discharge, flow velocity, water surface slopes, flow depth, and mean grain size. The deficiency of empirical equations for this river by conducted comparison between measured and predicted values was approved where the ANN models presented more consistence and closer estimation to observed data. The coefficient of determination between measured and predicted values for empirical equations varied from 0.10 to 0.21 against the 0.93 to 0.98 in ANN models. The accuracy performance of all models was evaluated and interpreted using different statistical error criteria, analytical graphs and confusion matrixes. Although the ANN models predicted compatible outputs but the RBF with 79% correct classification rate corresponding to 0.191 network error was outperform than others.

关键词： bed load prediction     artificial neural network     modeling     empirical equations    

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Special Column on Multiscale Stochastic Finite Element Method

《结构与土木工程前沿（英文）》 2015年 第9卷 第2期   页码 105-106 doi: 10.1007/s11709-015-0297-7

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Special column: solar energy conversion

Yun Hang HU, Fangming JIN

《能源前沿（英文）》 2019年 第13卷 第2期   页码 205-206 doi: 10.1007/s11708-019-0636-9

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Liquefaction and impurity separation of oxygen-bearing coal-bed methane

Qiuying LI, Yonglin JU, Li WANG,

《能源前沿（英文）》 2010年 第4卷 第3期   页码 319-325 doi: 10.1007/s11708-010-0115-9

摘要： Coal-bed methane (CBM) is a type of clean energy. However, most oxygen-bearing CBM have not yet to be utilized due to limited techniques, and when utilized, the discharged gas leads to resource wastage and environment pollution. In this paper, a liquefaction process is proposed and designed for the specified oxygen-bearing CBM obtained from the Daqing Qingshen gas field. The distillation column is employed to separate the oxygen and nitrogen components present in the CBM. HYSYS software is adopted to simulate the process, and the results reveal that the energy consumption of the whole liquefaction process is low. Moreover, oxygen and nitrogen are nearly removed completely, achieving a high-purity liquefied natural gas product with a high methane recovery rate. The applicability and safety of the liquefaction process are also analyzed. The simulation results can offer references for the separation of the oxygen component from CBM.

关键词： coal bed methane     oxygen-bearing     liquefaction     distillation    

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标题 作者 时间 类型 操作

Mass transfer mechanisms in fixed-bed adsorption of erythromycin

SUN Ying, ZHU Jiawen, CHEN Kui, ZHU Sheng, XU Jie

期刊论文

The coupling of sand with ZVI/oxidants achieved proportional and highly efficient removal of arsenic

Sana Ullah, Xuejun Guo, Xiaoyan Luo, Xiangyuan Zhang, Yameng Li, Ziyu Liang

期刊论文

Recovery of Ni(II) from real electroplating wastewater using fixed-bed resin adsorption and subsequent

Tong Li, Ke Xiao, Bo Yang, Guilong Peng, Fenglei Liu, Liyan Tao, Siyuan Chen, Haoran Wei, Gang Yu, Shubo Deng

期刊论文

Advances in the slurry reactor technology of the anthraquinone process for H

Hongbo Li, Bo Zheng, Zhiyong Pan, Baoning Zong, Minghua Qiao

期刊论文

Migration of manganese and iron during the adsorption-regeneration cycles for arsenic removal

Fangfang CHANG, Jiuhui QU, Xu ZHAO, Wenjun LIU, Kun WU

期刊论文

Deactivation and regeneration of TS-1/SiO

Hainan SHI, Yaquan WANG, Guoqiang WU, Wenping FENG, Yi Lin, Teng ZHANG, Xing JIN, Shuhai WANG, Xiaoxue WU, Pengxu YAO

期刊论文

Reduction of hexavalent chromium with scrap iron in a fixed bed reactor

Yin WANG, Xuejiang WANG, Xin WANG, Mian LIU, Siqing XIA, Daqiang YIN, Yalei ZHANG, Jianfu ZHAO

期刊论文

Investigation of fluorescence characterization and electrochemical behavior on the catalysts of nanosized Pt-Rh/γ-Al

Chang-Mao HUNG, Wen-Liang LAI, Jane-Li LIN

期刊论文

Preparation and characterization of novel carbon molecular sieve membrane/PSSF composite by pyrolysis method for toluene adsorption

Ying Yan, Peng Huang, Huiping Zhang

期刊论文

Special Column on

期刊论文

Simulation of bubble column reactors using CFD coupled with a population balance model

Tiefeng WANG

期刊论文

Prediction of bed load sediments using different artificial neural network models

Reza ASHEGHI, Seyed Abbas HOSSEINI

期刊论文

Special Column on Multiscale Stochastic Finite Element Method

期刊论文

Special column: solar energy conversion

Yun Hang HU, Fangming JIN

期刊论文

Liquefaction and impurity separation of oxygen-bearing coal-bed methane

Qiuying LI, Yonglin JU, Li WANG,

期刊论文